Unlock All Characters
After each character has been unlocked, they have to be purchased in the Shop before you can play as them. Also, in order to play as Berserk EVA 01, EVA 00 Kai, and Bardiel, you need to hold down [L1] while selecting EVA 01, EVA 00, and EVA 03.
Bardiel - Clear Story Mode on Hard with EVA 03.
Berserk EVA 01 - Clear Story Mode on Hard with EVA 01.
EVA 00 Kai (Blue) - Clear Story Mode on Normal with EVA 00.
EVA 03 - Clear Story Mode with EVA 00, 01, & 02.
EVA 04 - Clear Story Mode on Normal with EVA 03.
EVA Kou - Defeat in Endless Mode (Enemy 41).
EVA MP (Mass-Production) - Defeat in Story Mode with EVA 02.
EVA Otsu (Kaworu) - Clear Story Mode on Normal with EVA 04.
Gaghiel - Defeat in Story Mode with EVA 02.
Gunbuster - Defeat in Endless Mode (Enemy 46).
Israfel - Defeat in Story Mode with EVA 02.
Jet Alone - Defeat in Story Mode with EVA 03.
Leliel - Defeat in Story Mode with EVA 00.
Ramiel - Defeat in Story Mode with EVA 00 or EVA 01.
Sachiel - Defeat in Story Mode with EVA 00 or EVA 01.
Sahaqiel - Defeat in Story Mode with EVA 00, 01, or 02.
Shamshiel - Defeat in Story Mode with EVA 01.
Zeruel - Defeat in Story Mode with EVA 00 or EVA 02.