Unlock Characters
Aizen Sousuke - Clear Arcade Mode with Ulquiorra
Arturo Plateado - Unknown (in relation to Story Mode)
Grimmjow Jaggerjack - Clear Arcade Mode with Aizen Sousuke
Hinamori Momo - Unknown (in relation to Story Mode)
Hisagi Shuuhei - Unknown (in relation to Story Mode)
Ichimaru Gin - Clear Arcade Mode with Matsumoto Rangiku
Kuchiki Rukia - Unknown (in relation to Story Mode)
Kurotsuchi Mayuri - Clear Arcade Mode with Ishida Uryuu
Kusajishi Yachiru - Clear Arcade Mode with Yumichika Ayasegawa
Kyouraku Shunsui - Clear Arcade Mode with Sado Yasutora
Madarame Ikkaku - Unknown (in relation to Story Mode)
Shihouin Yoruichi - Clear Training Mode
Soi Fon - Unknown (in relation to Story Mode)
Tousen Kaname - Clear Arcade Mode with Komamura Sajin
Ukitake Juushiro - Clear Arcade Mode with Kyouraku Shunsui
Ulquiorra - Clear Arcade Mode with Ichimaru Gin
Urahara Kisuke - Clear Arcade Mode with Kurotsuchi Mayuri
Yamada Hanatarou - Unknown (in relation to Story Mode)
Yamamoto Genryuusai Shigekuni - Clear Arcade Mode with Ukitake Juushiro
Yumichika Ayasegawa - Clear Arcade Mode with Madarame Ikkaku
Unlock Costumes
Hitsugaya School Costume - Clear Arcade Mode with Toushiro Hitsugaya.
Ikkaku School Costume - Clear Arcade Mode with Madarame Ikkaku again after unlocking all characters.
Renji School Costume - Clear Arcade Mode with Abarai Renji.
Shihouin Yoruichi Shunpo Costume - Clear Arcade mode with Shihouin Yoruichi and complete the Tutorial mode.
Urahara Kisuke Shinigami Costume - Unlock Everything.
Yumichika School Costume - Clear Arcade Mode with Ayasegawa Yumichika again after unlocking all characters.
Unlock Stages
Arturo Battle Stage - Defeat Arturo Plateado on the final stage of episode mode.
Ice Haven - Complete Hitsugaya's episode mode.